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dc.contributor.authorKaraman, Rafik
dc.date.accessioned2018-09-03T10:32:05Z
dc.date.available2018-09-03T10:32:05Z
dc.date.issued2009-02-10
dc.identifier.issn1875-6255
dc.identifier.urihttps://dspace.alquds.edu/handle/20.500.12213/804
dc.description.abstractDFT at B3LYP/6-31G(d, p) and HF at 6-31G and AM1 semiempirical calculations of thermodynamc and kinetic parameters for the trimethyl lock system (an important enzyme model) indicate that the remarkable enhancement in the lactonizations is largely the result of a proximity orientation as opposed to the currently advanced strain effect.en_US
dc.description.sponsorshipThe author thanks the Karamans Co. and the German- Palestinian-Israeli fund agency for support of our hardware computational facilities. Special thanks go to Dr. Omar Deeb and Sherin Alfalah and Donia Karaman for support in computational software and technical assistance. His sincere appreciations are given to Professor Fred Menger (Emory University, Ga, USA) for helpful discussions.en_US
dc.language.isoen_USen_US
dc.publisherHindawi Publishing Corporationen_US
dc.titleAccelerations in the Lactonization of Trimethyl Lock Systems Aredue to Proximity Orientation and not to Strain Effectsen_US
dc.typeArticleen_US


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