Accelerations in the Lactonization of Trimethyl Lock Systems Aredue to Proximity Orientation and not to Strain Effects

dc.contributor.author Karaman, Rafik
dc.date.accessioned 2018-09-03T10:32:05Z
dc.date.available 2018-09-03T10:32:05Z
dc.date.issued 2009-02-10
dc.description.abstract DFT at B3LYP/6-31G(d, p) and HF at 6-31G and AM1 semiempirical calculations of thermodynamc and kinetic parameters for the trimethyl lock system (an important enzyme model) indicate that the remarkable enhancement in the lactonizations is largely the result of a proximity orientation as opposed to the currently advanced strain effect. en_US
dc.description.sponsorship The author thanks the Karamans Co. and the German- Palestinian-Israeli fund agency for support of our hardware computational facilities. Special thanks go to Dr. Omar Deeb and Sherin Alfalah and Donia Karaman for support in computational software and technical assistance. His sincere appreciations are given to Professor Fred Menger (Emory University, Ga, USA) for helpful discussions. en_US
dc.identifier.issn 1875-6255
dc.identifier.uri https://dspace.alquds.edu/handle/20.500.12213/804
dc.language.iso en_US en_US
dc.publisher Hindawi Publishing Corporation en_US
dc.title Accelerations in the Lactonization of Trimethyl Lock Systems Aredue to Proximity Orientation and not to Strain Effects en_US
dc.type Article en_US
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