Spectrophotometric Determination of Cu2+ Metal Ions via Complex Formation with Carboxylated Tris(2-aminoethyl)amine

dc.contributor.authorShakhshir, Ziad M.
dc.contributor.authorMasharqah, Julnar
dc.contributor.authorOdeh, Imad
dc.contributor.authorJondi, Waheed J.
dc.contributor.authorAbu Shqair, Ibrahim
dc.date.accessioned2018-09-09T13:03:31Z
dc.date.available2018-09-09T13:03:31Z
dc.date.issued2016-01-15
dc.description.abstractAn aminopolycarboxylic acid chelating agent; tris(2-aminoethyl)aminehexaacetic acid (TAHA) was prepared and characterized. TAHA formed stable complexes with Cu(II) ions and other metal ions at pH 10. The complexation behavior was studied by spectrophotometry at the complex maximum wavelength. Mixtures of Cu(II) and other metal ions (M2+; Ca2+, Co2+, Ni2+, Cd2+) were titrated with TAHA at pH 10. The stoichiometry of ligand - to - metal was found to be 1:1. The stability constant of Cu(II)–TAHA complex was determined to be 1.86×105 by using the continuous variation method. Beer’s law was obeyed over the concentration range 3.0×10–4 M – 1.2×10–2 M for Cu(II) solution. The results of the quantitative determination of Cu(II) gave LOD and LOQ values of 7.285×10–6 M and 2.428×10–5 M respectively. The percent relative standard deviation (%RSD) for five replicate samples was found to be 1.088% and 4.804% for Cu(II) concentrations of 1.2×10–2 M and 3.0×10–4 M respectively.en_US
dc.identifier.issn2321-807X
dc.identifier.urihttps://dspace.alquds.edu/handle/20.500.12213/876
dc.language.isoen_USen_US
dc.publisherCouncil for Innovative Researchen_US
dc.subjectTris(2-aminoethyl)aminehexaacetic aciden_US
dc.subjectcomplexationen_US
dc.subjectspectrophotometryen_US
dc.titleSpectrophotometric Determination of Cu2+ Metal Ions via Complex Formation with Carboxylated Tris(2-aminoethyl)amineen_US
dc.typeArticleen_US
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