TiO2 and Active Coated Glass Photodegradation of Ibuprofen

dc.contributor.authorKhalaf, Samer
dc.contributor.authorShoqeir, Jawad H.
dc.contributor.authorLelario, Filomena
dc.contributor.authorBufo, Sabino A.
dc.contributor.authorKaraman, Rafik
dc.contributor.authorScrano, Laura
dc.date.accessioned2020-07-21T11:58:47Z
dc.date.available2020-07-21T11:58:47Z
dc.date.issued2020-05-18
dc.description.abstractCommercial non-steroidal anti-inflammatory drugs (NSAIDs) are considered as toxic to the environment since they induce side e ects when consumed by humans or aquatic life. Ibuprofen is a member of the NSAID family and is widely used as an anti-inflammatory and painkiller agent. Photolysis is a potentially important method of degradation for several emerging contaminants, and individual compounds can undergo photolysis to various degrees, depending on their chemical structure. The e ciency oftitanium dioxide (TiO2) and photocatalysis was investigated for the removal of ibuprofen from the aquatic environment, and the performance of these di erent processes was evaluated. In heterogeneous photocatalysis, two experiments were carried out using TiO2 as (i) dispersed powder, and (ii) TiO2 immobilized on the active surface of commercial coated glass. The kinetics of each photoreaction was determined, and the identification of the photoproducts was carried out by liquid chromatography coupled with Fourier-transform ion cyclotron resonance mass spectrometry (LC-FTICR MS). The overall results suggest that the TiO2 active thin layer immobilized on the glass substrate can avoid recovery problems related to the use of TiO2 powder in heterogeneous photocatalysis and may be a promising tool toward protecting the environment from emerging contaminants such as ibuprofen and its derivatives.en_US
dc.description.sponsorshipFunding: This work was supported by the European Union in the framework of the Project “Di usion of nanotechnology-based devices for water treatment and recycling; NANOWAT” (ENPI CBC MED I-B/2.1/049, Grant No. 7/1997). Acknowledgments: Many thanks to Jawad H. Shoqueir, the head of Soil and hydrology Lab at Al-Quds University, for his support to partially cover the publication fee from his own budget. Results reported in this article were partially presented by Samer Khalaf at the Second International Conference on Recycle and Reuse, 4–6 June 2014, Istanbul, Turkey and published in the book of abstracts.en_US
dc.identifier.urihttps://dspace.alquds.edu/handle/20.500.12213/5728
dc.language.isoenen_US
dc.publisherMDPIen_US
dc.subjectibuprofenen_US
dc.subjectadvanced oxidation processen_US
dc.subjectTiO2en_US
dc.subjectphotocatalysisen_US
dc.subjectactive glassen_US
dc.titleTiO2 and Active Coated Glass Photodegradation of Ibuprofenen_US
dc.typeArticleen_US
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